Образование и опыт работы
1998 - 2004 гг. Московская Государственная академия тонкой химической технологии им. М.В. Ломоносова (МИТХТ), (диплом с отличием).
2004 - 2007 гг. аспирантура Московской Государственной академии тонкой химической технологии, специальность «Химия элементоорганических соединений», кандидат химических наук.
2004 - 2007 гг. младший научный сотрудник кафедры ХТЭОС (МИТХТ),
2007 - 2011 гг. ассистент кафедры ХТЭОС (МИТХТ),
2011 - 2014 гг. доцент кафедры ХТЭОС (МИТХТ),
2014 - 2016 гг. научный сотрудник Лаборатории металлокомплексных и наноразмерных катализаторов Института органической химии им. Н. Д. Зелинского РАН.
2016 по н.в. старший научный сотрудник Лаборатории металлокомплексных и наноразмерных катализаторов Института органической химии им. Н. Д. Зелинского РАН.
Область научных интересов:
Молекулярное моделирование в изучении строения вещества, механизмов химических реакций и свойств материалов; применение аддитивных технологий в химии.
Публикации
1. G.M. Averochkin, E.G. Gordeev, F.A. Kucherov, V.P. Ananikov, Rapid access to molecular complexity from bioderived 5-HMF derivatives via cascade cycloadditions, Green Chem., 2023, 25, 1045-1055, DOI: 10.1039/d2gc04197a.
2. R.R. Shaydullin, A.S. Galushko, E.O. Pentsak, V.M. Korshunov, I.V. Taydakov, E.G. Gordeev, M.E. Minyaev, D.I. Nasyrova, V.P. Ananikov, Yellow to blue switching of fluorescence by the tuning of the pentaphenylphosphole structure: phosphorus electronic state vs. ring conjugation, Phys. Chem. Chem. Phys., 2022, 24, 25307-25315, DOI: 10.1039/D2CP03723H.
3. A.Yu. Kostyukovich, E.G. Gordeev, V.P. Ananikov, A computational mapping of the R-NHC coupling pathway – the key process in the evolution of Pd/NHC catalytic systems, Mendeleev Comm., 2022, 32, pp. 571-575, DOI: 10.1016/j.mencom.2022.09.001.
4. K.S. Egorova, M.M. Seitkalieva, A.S. Kashin, E.G. Gordeev, A.V. Vavina, A.V. Posvyatenko, V.P. Ananikov, Biological activity, solvation properties and microstructuring of protic imidazolium ionic liquids, J. Mol. Liq., 2022, 367, 120450, DOI: 10.1016/j.molliq.2022.120450.
5. D.A. Boiko, V.A. Korabelnikova, E.G. Gordeev, V.P. Ananikov, Integration of thermal imaging and neural networks for mechanical strength analysis and fracture prediction in 3D-printed plastic parts, Sci. Rep., 2022, 12, 8944, DOI: 10.1038/s41598-022-12503-y.
6. E.G. Gordeev, K.S. Erokhin, A.D. Kobelev, J.V. Burykina, P.V. Novikov, V.P. Ananikov, Exploring metallic and plastic 3D printed photochemical reactors for customizing chemical synthesis, Sci. Rep., 2022, 12, 3780, DOI: 10.1038/s41598-022-07583-9.
7. A.V. Vavina, M.S. Seitkalieva, A.V. Posvyatenko, E.G. Gordeev, E.N. Strukova, K.S. Egorova, V.P. Ananikov, Merging structural frameworks of imidazolium, pyridinium, and cholinium ionic liquids with cinnamic acid to tune solution state behavior and properties, J. Mol. Liq., 2022, 352, 118673, DOI: 10.1016/j.molliq.2022.118673.
8. D.V. Pasyukov, M.A. Shevchenko, K.E. Shepelenko, O.V. Khazipov, J.V. Burykina, E.G. Gordeev, M.E. Minyaev, V.M. Chernyshev, V.P. Ananikov, One-Step Access to Heteroatom-Functionalized Imidazol(in)ium Salts, Angew. Chem. Int. Ed., 2022, e202116131, DOI: 10.1002/anie.202116131.
9. K.S. Erokhin, E.G. Gordeev, D.E. Samoylenko, K.S. Rodygin, V.P. Ananikov, 3D Printing to Increase the Flexibility of the Chemical Synthesis of Biologically Active Molecules: Design of On-Demand Gas Generation Reactors, Int. J. Mol. Sci., 2021, 22, 18, 9919, DOI: 10.3390/ijms22189919.
10. L.T. Sahharova, E.G. Gordeev, D.B. Eremin, V.P. Ananikov, Computational Design of Radical Recognition Assay with the Possible Application of Cyclopropyl Vinyl Sulfides as Tunable Sensors, Int. J. Mol. Sci., 2021, 22, 14, 7637, DOI: 10.3390/ijms22147637.
11. A.Yu. Chernenko, A.V. Astakhov, V.V. Kutyrev, E.G. Gordeev, J.V. Burykina, M.E. Minyaev, V.N. Khrustalev, V.M. Chernyshev, V.P. Ananikov, Stabilization of the Pd–NHC framework with 1,2,4-triazol-5-ylidene ligands toward decomposition in alkaline media, Inorg. Chem. Front., 2021, 8, 13, 3382-3401, DOI: 10.1039/D1QI00453K.
12. G.M. Averochkin, E.G. Gordeev, M.K. Skorobogatko, F.A. Kucherov, V.P. Ananikov, Systematic study of aromatic-ring-targeted cycloadditions of HMF platform chemicals, ChemSusChem, 14, 15, 2021, 3110-3123, DOI: 10.1002/cssc.202100818.
13. D.A. Boiko, E.O. Pentsak, V.A. Cherepanova, E.G. Gordeev, V.P. Ananikov, Deep neural network analysis of nanoparticle ordering to identify defects in layered carbon materials, Chem. Sci., 2021, 12, 7428-7441, DOI: 10.1039/D0SC05696K.
14. M.M. Seitkalieva, A.V. Vavina, A.V. Posvyatenko, K.S. Egorova, A.S. Kashin, E.G. Gordeev, E.N. Strukova, L.V. Romashov, V.P. Ananikov, Biomass-Derived Ionic Liquids Based on a 5-HMF Platform Chemical: Synthesis, Characterization, Biological Activity, and Tunable Interactions at the Molecular Level, ACS Sustainable Chem. Eng., 2021, 9, 3552-3570, DOI: 10.1021/acssuschemeng.0c08790.
15. K.I. Galkin, E.G. Gordeev, V.P. Ananikov, Organocatalytic Deuteration Induced by the Dynamic Covalent Interaction of Imidazolium Cations with Ketones, Adv. Synth. Catal., 2021, 363, 1368-1378, DOI: 10.1002/adsc.202001507.
16. A.S. Galushko, E.G. Gordeev, A.S. Kashin, Y.V. Zubavichus, V.P. Ananikov, Visualization of catalyst dynamics and development of a practical procedure to study complex "cocktail"?type catalytic systems, Faraday Discuss., 2021, 229, 458-474, DOI: 10.1039/C9FD00125E.
17. E.G. Gordeev, V.P. Ananikov, Widely accessible 3D printing technologies in chemistry, biochemistry and pharmaceutics: applications, materials and prospects, Russ. Chem. Rev., 2020, 89 (12), pp. 1507-1561, DOI: 10.1070/RCR4980.
18. F.A. Kucherov, E.G. Gordeev, A.S. Kashin, V.P. Ananikov, Controlled Natural Biomass Deoxygenation Allows the Design of Reusable Hot-Melt Adhesives Acting in a Multiple Oxygen Binding Mode, ACS Appl. Mater. Interfaces, 2020, 12, 40, 45394-45403, DOI: 10.1021/acsami.0c14986.
19. E.O. Pentsak, E.G. Gordeev, V.P. Ananikov, Carbocatalysis: From Acetylene Trimerization to Modern Organic Synthesis. A Review, Doklady Physical Chemistry, 2020, vol. 493, pp. 95-122, DOI: 10.1134/S0012501620380017.
20. L.T. Sahharova, E.G. Gordeev, D.B. Eremin, V.P. Ananikov, Pd-Catalyzed Synthesis of Densely Functionalized Cyclopropyl Vinyl Sulfides Reveals the Origin of High Selectivity in a Fundamental Alkyne Insertion Step, ACS Catal., 2020, 10, 9872-9888, DOI: 10.1021/acscatal.0c02053.
21. J.V. Burykina, N.S. Shlapakov, E.G. Gordeev, B. K?enig, V.P. Ananikov, Selectivity control in thiol-yne click reactions via visible light induced associative electron upconversion, Chem. Sci., 2020, 11, 10061-10070, DOI: 10.1039/D0SC01939A.
22. K.I. Galkin, B.Ya. Karlinskii, A.Yu. Kostyukovich, E.G. Gordeev, V.P. Ananikov, Ambident Reactivity of Imidazolium Cations as Evidence of the Dynamic Nature of N?Heterocyclic Carbene?Mediated Organocatalysis, Chem. Eur. J., 2020, 26, pp. 8567-8571, DOI: 10.1002/chem.201905704.
23. E.G. Gordeev, E.O. Pentsak, V.P. Ananikov, Carbocatalytic Acetylene Cyclotrimerization: A Key Role of Unpaired Electron Delocalization, J. Am. Chem. Soc., 2020, 142, 8, 3784-3796, DOI: 10.1021/jacs.9b10887.
24. K.S. Erokhin, E.G. Gordeev, V.P. Ananikov, Revealing interactions of layered polymeric materials at solid-liquid interface for building solvent compatibility charts for 3D printing applications, Scientific Reports, 2019, 9, 20177, DOI: 10.1038/s41598-019-56350-w.
25. A. Astakhov, S. Soliev, E. Gordeev, V. Chernyshev, V. Ananikov, Relative Stability of M/NHC Complexes (M = Ni, Pd, Pt) against R?NHC, X?NHC and X?X Couplings in M(0)/M(II) and M(II)/M(IV) Catalytic Cycles: a Theoretical Study, Dalton Transactions, 2019, 48, 17052-17062, DOI: 10.1039/C9DT03266E.
26. E.A. Denisova, D.B. Eremin, E.G. Gordeev, A.M. Tsedilin, V.P. Ananikov, Addressing Reversibility of R–NHC Coupling on Palladium: Is Nano-to-Molecular Transition Possible for the Pd/NHC System? Inorg. Chem., 2019, 58, 18, 12218-12227, DOI: 10.1021/acs.inorgchem.9b01630.
27. E.O. Pentsak, D.B. Eremin, E.G. Gordeev, V.P. Ananikov, Phantom Reactivity in Organic and Catalytic Reactions as a Consequence of Microscale Destruction and Contamination-Trapping Effects of Magnetic Stir Bars, ACS Catal., 2019, 9, 3070-3081, DOI: 10.1021/acscatal.9b00294.
28. E.G. Gordeev, V.P. Ananikov, Switching the nature of catalytic centers in Pd/NHC systems by solvent effect driven non?classical R?NHC Coupling, J. Comput. Chem., 2019, 40, 191-199, DOI: 10.1002/jcc.25572.
29. A.S. Galushko, E.G. Gordeev, V.P. Ananikov, High-Performance Synthesis of Phosphorus-Doped Graphene Materials and Stabilization of Phosphoric Micro- and Nanodroplets, Langmuir, 2018, 34, 51, 15739-15748, DOI: 10.1021/acs.langmuir.8b03417.
30. E.G. Gordeev, A.S. Galushko, V.P. Ananikov, Improvement of quality of 3D printed objects by elimination of microscopic structural defects in fused deposition modeling, PLoS ONE, 2018, 13(6): e0198370, DOI: 10.1371/journal.pone.0198370.
31.G.A. Abakumov, A.V. Piskunov, V.K. Cherkasov, I.L. Fedushkin, V.P. Ananikov, D.B. Eremin, E.G. Gordeev, I.P. Beletskaya, A.D. Averin, M.N. Bochkarev, A.A. Trifonov, U.M. Dzhemilev, V.A. Dyakonov, M.P. Egorov, A.N. Vereshchagin, M.A. Syroeshkin, V.V. Zhuikov, A.M. Muzafarov, A.A. Anisimov, A.V. Arzumanyan, Yu.N. Kononevich, M.N. Temnikov, O.G. Sinyashin, Yu.H. Budnikova, A.R. Burilov, A.A. Karasik, V.F. Mironov, P.A. Storozhenko, G.I. Shcherbakova, B.A. Trofimov, S.V. Amosova, N.K. Gusarova, V.A. Potapov, V.B. Shur, V.V. Burlakov, V.S. Bogdanov, M.V. Andreev, Organoelement chemistry: promising areas of growth and challenges, Russ. Chem. Rev., 2018, 87 (5), 393-507.
32. V.V. Voronin, M.S. Ledovskaya, E.G. Gordeev, K.S. Rodygin, V.P. Ananikov, [3 + 2]-Cycloaddition of in Situ Generated Nitrile Imines and Acetylene for Assembling of 1,3-Disubstituted Pyrazoles with Quantitative Deuterium Labeling, J. Org. Chem., 2018, 83, 3819-3828, DOI: 10.1021/acs.joc.8b00155.
33. E.G. Gordeev, D.B. Eremin, V.M. Chernyshev, V.P. Ananikov, Influence of R–NHC Coupling on the Outcome of R–X Oxidative Addition to Pd/NHC Complexes (R = Me, Ph, Vinyl, Ethynyl), Organometallics, 2018, 37, 787-796, DOI: 10.1021/acs.organomet.7b00669.
34. F. Kucherov, E. Gordeev, A. Kashin, V. Ananikov, 3D printing with biobased PEF for carbon neutral manufacturing, Angew. Chem. Int. Ed., 2017, 56, 15931-15935, DOI: 10.1002/anie.201708528.
35. F. Kucherov, K. Galkin, E. Gordeev, V. Ananikov, Efficient route for the construction of polycyclic systems from bioderived HMF, Green Chem., 2017, 19, pp. 4858-4864, DOI: 10.1039/C7GC02211E.
36. G. Werner, K.S. Rodygin, A.A. Kostin, E.G. Gordeev, A.S. Kashin, V.P. Ananikov, A solid acetylene reagent with enhanced reactivity: fluoride-mediated functionalization of alcohols and phenols, Green Chem., 2017, 19, pp. 3032-3041, DOI: 10.1039/C7GC00724H.
37. A.V. Astakhov, O.V. Khazipov, A.Yu. Chernenko, D.V. Pasyukov, A.S. Kashin, E.G. Gordeev, V.N. Khrustalev, V.M. Chernyshev, V.P. Ananikov, A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki-Heck Reaction, Organometallics, 2017, 36, pp. 1981-1992, DOI: 10.1021/acs.organomet.7b00184.
38. K.S. Egorova, E.G. Gordeev, V.P. Ananikov, Biological Activity of Ionic Liquids and Their Application in Pharmaceutics and Medicine, Chem. Rev., 2017, 117, pp. 7132–7189, DOI: 10.1021/acs.chemrev.6b00562.
39. E.G. Gordeev, E.S. Degtyareva, V.P. Ananikov, Analysis of 3D printing possibilities for the development of practical applications in synthetic organic chemistry, Russ. Chem. Bull., Int. Ed., 2016, 65, № 6, pp. 1637-1643, DOI: 10.1007/s11172-016-1492-y.
40. A.E. Sedykh, E. G. Gordeev, E. O. Pentsak, V. P. Ananikov, Shielding the chemical reactivity using graphene layers for controlling the surface properties of carbon materials, Phys. Chem. Chem. Phys., 2016, Vol. 18, pp. 4608-4616; DOI: 10.1039/C5CP05586E.
41. E.S. Degtyareva, J.V. Burykina, A.N. Fakhrutdinov, E.G. Gordeev, V.N. Khrustalev, V.P. Ananikov, Pd-NHC Catalytic System for the Efficient Atom-Economic Synthesis of Vinyl Sulfides from Tertiary, Secondary, or Primary Thiols, ACS Catal., 2015, Vol. 5, pp. 7208?7213, DOI: 10.1021/acscatal.5b01815.
42. E.G. Gordeev, V.P. Ananikov, Computational Study of a Model System of Enzyme-Mediated [4+2] Cycloaddition Reaction, PLoS ONE, 2015, 10(4): e0119984, DOI:10.1371/journal.pone.0119984.
43. L.V. Romashov, L.L. Khemchyan, E.G. Gordeev, I.O. Koshevoy, S.P. Tunik, V.P. Ananikov, Design of a Bimetallic Au/Ag System for Dechlorination of Organochlorides: Experimental and Theoretical Evidence for the Role of the Cluster Effect, Organometallics, 2014, Vol. 33, pp. 6003-6012. DOI: 10.1021/om500620u.
44. E.O. Pentsak, E.G. Gordeev, V.P. Ananikov, Noninnocent Nature of Carbon Support in Metal/Carbon Catalysts: Etching/Pitting vs Nanotube Growth under Microwave Irradiation, ACS Catalysis, 2014, Vol. 4, pp. 3806-3814, DOI: 10.1021/cs500934g.
45. O.V. Zatolochnaya, E.G. Gordeev, C. Jahier, V.P. Ananikov, V. Gevorgyan, Carboxylate Switch between Hydro- and Carbopalladation Pathways in Regiodivergent Dimerization of Alkynes, Chemistry – A European Journal, 2014 , Vol. 20, Issue 31, pp. 9578-9588, DOI: 10.1002/chem.201402809.
46. E.G. Gordeev, M.V. Polynski, V.P. Ananikov, «Fast and accurate computational modeling of adsorption on graphene: a dispersion interaction challenge», Phys. Chem. Chem. Phys., 2013, 15, 18815-18821, DOI: 10.1039/c3cp53189a.
47. V.P. Ananikov, E.G. Gordeev, «Novel [4 + 2] cycloaddition reactions of alkyne and enyne key-units: Direct access to bicyclic aromatic and heteroaromatic products. A theoretical mechanistic study», Chemical Science, 2011, 2, 2332-2341, DOI: 10.1039/C1SC00380A.
Хобби
Компьютерная графика, фотография.
