Education and research experience
1998 - 2004 – Moscow State Academy of Fine Chemical Technology (diploma with honors).
2004 - 2007 – Postgraduate course at the Moscow State Academy of Fine Chemical Technology, specialty "Chemistry of organoelement compounds," PhD in Chemistry.
2004 - 2007 – Junior Researcher at the Department of Chemistry and Technology of Organoelement Compounds (Moscow State Academy of Fine Chemical Technology),
2007 - 2011 – Assistant of the Department of the Chemistry and Technology of Organoelement Compounds (Moscow State Academy of Fine Chemical Technology),
2011 - 2014 – Associate Professor of the Department of the Chemistry and Technology of Organoelement Compounds (Moscow State Academy of Fine Chemical Technology),
2014 - 2016 – Researcher at the Laboratory of Metal-Complex and Nanoscale Catalysts (N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences).
2016 to present – Senior Researcher at the Laboratory of Metal-Complex and Nanoscale Catalysts (N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences).
Research interests
Molecular modeling in the study of matter structure, mechanisms of chemical reactions and material science; application of additive manufacturing in chemistry.
Publications:
1. G.M. Averochkin, E.G. Gordeev, F.A. Kucherov, V.P. Ananikov, Rapid access to molecular complexity from bioderived 5-HMF derivatives via cascade cycloadditions, Green Chem., 2023, 25, 1045-1055, DOI: 10.1039/d2gc04197a.
2. R.R. Shaydullin, A.S. Galushko, E.O. Pentsak, V.M. Korshunov, I.V. Taydakov, E.G. Gordeev, M.E. Minyaev, D.I. Nasyrova, V.P. Ananikov, Yellow to blue switching of fluorescence by the tuning of the pentaphenylphosphole structure: phosphorus electronic state vs. ring conjugation, Phys. Chem. Chem. Phys., 2022, 24, 25307-25315, DOI: 10.1039/D2CP03723H.
3. A.Yu. Kostyukovich, E.G. Gordeev, V.P. Ananikov, A computational mapping of the R-NHC coupling pathway – the key process in the evolution of Pd/NHC catalytic systems, Mendeleev Comm., 2022, 32, pp. 571-575, DOI: 10.1016/j.mencom.2022.09.001.
4. K.S. Egorova, M.M. Seitkalieva, A.S. Kashin, E.G. Gordeev, A.V. Vavina, A.V. Posvyatenko, V.P. Ananikov, Biological activity, solvation properties and microstructuring of protic imidazolium ionic liquids, J. Mol. Liq., 2022, 367, 120450, DOI: 10.1016/j.molliq.2022.120450.
5. D.A. Boiko, V.A. Korabelnikova, E.G. Gordeev, V.P. Ananikov, Integration of thermal imaging and neural networks for mechanical strength analysis and fracture prediction in 3D-printed plastic parts, Sci. Rep., 2022, 12, 8944, DOI: 10.1038/s41598-022-12503-y.
6. E.G. Gordeev, K.S. Erokhin, A.D. Kobelev, J.V. Burykina, P.V. Novikov, V.P. Ananikov, Exploring metallic and plastic 3D printed photochemical reactors for customizing chemical synthesis, Sci. Rep., 2022, 12, 3780, DOI: 10.1038/s41598-022-07583-9.
7. A.V. Vavina, M.S. Seitkalieva, A.V. Posvyatenko, E.G. Gordeev, E.N. Strukova, K.S. Egorova, V.P. Ananikov, Merging structural frameworks of imidazolium, pyridinium, and cholinium ionic liquids with cinnamic acid to tune solution state behavior and properties, J. Mol. Liq., 2022, 352, 118673, DOI: 10.1016/j.molliq.2022.118673.
8. D.V. Pasyukov, M.A. Shevchenko, K.E. Shepelenko, O.V. Khazipov, J.V. Burykina, E.G. Gordeev, M.E. Minyaev, V.M. Chernyshev, V.P. Ananikov, One-Step Access to Heteroatom-Functionalized Imidazol(in)ium Salts, Angew. Chem. Int. Ed., 2022, e202116131, DOI: 10.1002/anie.202116131.
9. K.S. Erokhin, E.G. Gordeev, D.E. Samoylenko, K.S. Rodygin, V.P. Ananikov, 3D Printing to Increase the Flexibility of the Chemical Synthesis of Biologically Active Molecules: Design of On-Demand Gas Generation Reactors, Int. J. Mol. Sci., 2021, 22, 18, 9919, DOI: 10.3390/ijms22189919.
10. L.T. Sahharova, E.G. Gordeev, D.B. Eremin, V.P. Ananikov, Computational Design of Radical Recognition Assay with the Possible Application of Cyclopropyl Vinyl Sulfides as Tunable Sensors, Int. J. Mol. Sci., 2021, 22, 14, 7637, DOI: 10.3390/ijms22147637.
11. A.Yu. Chernenko, A.V. Astakhov, V.V. Kutyrev, E.G. Gordeev, J.V. Burykina, M.E. Minyaev, V.N. Khrustalev, V.M. Chernyshev, V.P. Ananikov, Stabilization of the Pd–NHC framework with 1,2,4-triazol-5-ylidene ligands toward decomposition in alkaline media, Inorg. Chem. Front., 2021, 8, 13, 3382-3401, DOI: 10.1039/D1QI00453K.
12. G.M. Averochkin, E.G. Gordeev, M.K. Skorobogatko, F.A. Kucherov, V.P. Ananikov, Systematic study of aromatic-ring-targeted cycloadditions of HMF platform chemicals, ChemSusChem, 14, 15, 2021, 3110-3123, DOI: 10.1002/cssc.202100818.
13. D.A. Boiko, E.O. Pentsak, V.A. Cherepanova, E.G. Gordeev, V.P. Ananikov, Deep neural network analysis of nanoparticle ordering to identify defects in layered carbon materials, Chem. Sci., 2021, 12, 7428-7441, DOI: 10.1039/D0SC05696K.
14. M.M. Seitkalieva, A.V. Vavina, A.V. Posvyatenko, K.S. Egorova, A.S. Kashin, E.G. Gordeev, E.N. Strukova, L.V. Romashov, V.P. Ananikov, Biomass-Derived Ionic Liquids Based on a 5-HMF Platform Chemical: Synthesis, Characterization, Biological Activity, and Tunable Interactions at the Molecular Level, ACS Sustainable Chem. Eng., 2021, 9, 3552-3570, DOI: 10.1021/acssuschemeng.0c08790.
15. K.I. Galkin, E.G. Gordeev, V.P. Ananikov, Organocatalytic Deuteration Induced by the Dynamic Covalent Interaction of Imidazolium Cations with Ketones, Adv. Synth. Catal., 2021, 363, 1368-1378, DOI: 10.1002/adsc.202001507.
16. A.S. Galushko, E.G. Gordeev, A.S. Kashin, Y.V. Zubavichus, V.P. Ananikov, Visualization of catalyst dynamics and development of a practical procedure to study complex "cocktail"?type catalytic systems, Faraday Discuss., 2021, 229, 458-474, DOI: 10.1039/C9FD00125E.
17. E.G. Gordeev, V.P. Ananikov, Widely accessible 3D printing technologies in chemistry, biochemistry and pharmaceutics: applications, materials and prospects, Russ. Chem. Rev., 2020, 89 (12), pp. 1507-1561, DOI: 10.1070/RCR4980.
18. F.A. Kucherov, E.G. Gordeev, A.S. Kashin, V.P. Ananikov, Controlled Natural Biomass Deoxygenation Allows the Design of Reusable Hot-Melt Adhesives Acting in a Multiple Oxygen Binding Mode, ACS Appl. Mater. Interfaces, 2020, 12, 40, 45394-45403, DOI: 10.1021/acsami.0c14986.
19. E.O. Pentsak, E.G. Gordeev, V.P. Ananikov, Carbocatalysis: From Acetylene Trimerization to Modern Organic Synthesis. A Review, Doklady Physical Chemistry, 2020, vol. 493, pp. 95-122, DOI: 10.1134/S0012501620380017.
20. L.T. Sahharova, E.G. Gordeev, D.B. Eremin, V.P. Ananikov, Pd-Catalyzed Synthesis of Densely Functionalized Cyclopropyl Vinyl Sulfides Reveals the Origin of High Selectivity in a Fundamental Alkyne Insertion Step, ACS Catal., 2020, 10, 9872-9888, DOI: 10.1021/acscatal.0c02053.
21. J.V. Burykina, N.S. Shlapakov, E.G. Gordeev, B. K?enig, V.P. Ananikov, Selectivity control in thiol-yne click reactions via visible light induced associative electron upconversion, Chem. Sci., 2020, 11, 10061-10070, DOI: 10.1039/D0SC01939A.
22. K.I. Galkin, B.Ya. Karlinskii, A.Yu. Kostyukovich, E.G. Gordeev, V.P. Ananikov, Ambident Reactivity of Imidazolium Cations as Evidence of the Dynamic Nature of N?Heterocyclic Carbene?Mediated Organocatalysis, Chem. Eur. J., 2020, 26, pp. 8567-8571, DOI: 10.1002/chem.201905704.
23. E.G. Gordeev, E.O. Pentsak, V.P. Ananikov, Carbocatalytic Acetylene Cyclotrimerization: A Key Role of Unpaired Electron Delocalization, J. Am. Chem. Soc., 2020, 142, 8, 3784-3796, DOI: 10.1021/jacs.9b10887.
24. K.S. Erokhin, E.G. Gordeev, V.P. Ananikov, Revealing interactions of layered polymeric materials at solid-liquid interface for building solvent compatibility charts for 3D printing applications, Scientific Reports, 2019, 9, 20177, DOI: 10.1038/s41598-019-56350-w.
25. A. Astakhov, S. Soliev, E. Gordeev, V. Chernyshev, V. Ananikov, Relative Stability of M/NHC Complexes (M = Ni, Pd, Pt) against R?NHC, X?NHC and X?X Couplings in M(0)/M(II) and M(II)/M(IV) Catalytic Cycles: a Theoretical Study, Dalton Transactions, 2019, 48, 17052-17062, DOI: 10.1039/C9DT03266E.
26. E.A. Denisova, D.B. Eremin, E.G. Gordeev, A.M. Tsedilin, V.P. Ananikov, Addressing Reversibility of R–NHC Coupling on Palladium: Is Nano-to-Molecular Transition Possible for the Pd/NHC System? Inorg. Chem., 2019, 58, 18, 12218-12227, DOI: 10.1021/acs.inorgchem.9b01630.
27. E.O. Pentsak, D.B. Eremin, E.G. Gordeev, V.P. Ananikov, Phantom Reactivity in Organic and Catalytic Reactions as a Consequence of Microscale Destruction and Contamination-Trapping Effects of Magnetic Stir Bars, ACS Catal., 2019, 9, 3070-3081, DOI: 10.1021/acscatal.9b00294.
28. E.G. Gordeev, V.P. Ananikov, Switching the nature of catalytic centers in Pd/NHC systems by solvent effect driven non?classical R?NHC Coupling, J. Comput. Chem., 2019, 40, 191-199, DOI: 10.1002/jcc.25572.
29. A.S. Galushko, E.G. Gordeev, V.P. Ananikov, High-Performance Synthesis of Phosphorus-Doped Graphene Materials and Stabilization of Phosphoric Micro- and Nanodroplets, Langmuir, 2018, 34, 51, 15739-15748, DOI: 10.1021/acs.langmuir.8b03417.
30. E.G. Gordeev, A.S. Galushko, V.P. Ananikov, Improvement of quality of 3D printed objects by elimination of microscopic structural defects in fused deposition modeling, PLoS ONE, 2018, 13(6): e0198370, DOI: 10.1371/journal.pone.0198370.
31.G.A. Abakumov, A.V. Piskunov, V.K. Cherkasov, I.L. Fedushkin, V.P. Ananikov, D.B. Eremin, E.G. Gordeev, I.P. Beletskaya, A.D. Averin, M.N. Bochkarev, A.A. Trifonov, U.M. Dzhemilev, V.A. Dyakonov, M.P. Egorov, A.N. Vereshchagin, M.A. Syroeshkin, V.V. Zhuikov, A.M. Muzafarov, A.A. Anisimov, A.V. Arzumanyan, Yu.N. Kononevich, M.N. Temnikov, O.G. Sinyashin, Yu.H. Budnikova, A.R. Burilov, A.A. Karasik, V.F. Mironov, P.A. Storozhenko, G.I. Shcherbakova, B.A. Trofimov, S.V. Amosova, N.K. Gusarova, V.A. Potapov, V.B. Shur, V.V. Burlakov, V.S. Bogdanov, M.V. Andreev, Organoelement chemistry: promising areas of growth and challenges, Russ. Chem. Rev., 2018, 87 (5), 393-507.
32. V.V. Voronin, M.S. Ledovskaya, E.G. Gordeev, K.S. Rodygin, V.P. Ananikov, [3 + 2]-Cycloaddition of in Situ Generated Nitrile Imines and Acetylene for Assembling of 1,3-Disubstituted Pyrazoles with Quantitative Deuterium Labeling, J. Org. Chem., 2018, 83, 3819-3828, DOI: 10.1021/acs.joc.8b00155.
33. E.G. Gordeev, D.B. Eremin, V.M. Chernyshev, V.P. Ananikov, Influence of R–NHC Coupling on the Outcome of R–X Oxidative Addition to Pd/NHC Complexes (R = Me, Ph, Vinyl, Ethynyl), Organometallics, 2018, 37, 787-796, DOI: 10.1021/acs.organomet.7b00669.
34. F. Kucherov, E. Gordeev, A. Kashin, V. Ananikov, 3D printing with biobased PEF for carbon neutral manufacturing, Angew. Chem. Int. Ed., 2017, 56, 15931-15935, DOI: 10.1002/anie.201708528.
35. F. Kucherov, K. Galkin, E. Gordeev, V. Ananikov, Efficient route for the construction of polycyclic systems from bioderived HMF, Green Chem., 2017, 19, pp. 4858-4864, DOI: 10.1039/C7GC02211E.
36. G. Werner, K.S. Rodygin, A.A. Kostin, E.G. Gordeev, A.S. Kashin, V.P. Ananikov, A solid acetylene reagent with enhanced reactivity: fluoride-mediated functionalization of alcohols and phenols, Green Chem., 2017, 19, pp. 3032-3041, DOI: 10.1039/C7GC00724H.
37. A.V. Astakhov, O.V. Khazipov, A.Yu. Chernenko, D.V. Pasyukov, A.S. Kashin, E.G. Gordeev, V.N. Khrustalev, V.M. Chernyshev, V.P. Ananikov, A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki-Heck Reaction, Organometallics, 2017, 36, pp. 1981-1992, DOI: 10.1021/acs.organomet.7b00184.
38. K.S. Egorova, E.G. Gordeev, V.P. Ananikov, Biological Activity of Ionic Liquids and Their Application in Pharmaceutics and Medicine, Chem. Rev., 2017, 117, pp. 7132–7189, DOI: 10.1021/acs.chemrev.6b00562.
39. E.G. Gordeev, E.S. Degtyareva, V.P. Ananikov, Analysis of 3D printing possibilities for the development of practical applications in synthetic organic chemistry, Russ. Chem. Bull., Int. Ed., 2016, 65, № 6, pp. 1637-1643, DOI: 10.1007/s11172-016-1492-y.
40. A.E. Sedykh, E. G. Gordeev, E. O. Pentsak, V. P. Ananikov, Shielding the chemical reactivity using graphene layers for controlling the surface properties of carbon materials, Phys. Chem. Chem. Phys., 2016, Vol. 18, pp. 4608-4616; DOI: 10.1039/C5CP05586E.
41. E.S. Degtyareva, J.V. Burykina, A.N. Fakhrutdinov, E.G. Gordeev, V.N. Khrustalev, V.P. Ananikov, Pd-NHC Catalytic System for the Efficient Atom-Economic Synthesis of Vinyl Sulfides from Tertiary, Secondary, or Primary Thiols, ACS Catal., 2015, Vol. 5, pp. 7208?7213, DOI: 10.1021/acscatal.5b01815.
42. E.G. Gordeev, V.P. Ananikov, Computational Study of a Model System of Enzyme-Mediated [4+2] Cycloaddition Reaction, PLoS ONE, 2015, 10(4): e0119984, DOI:10.1371/journal.pone.0119984.
43. L.V. Romashov, L.L. Khemchyan, E.G. Gordeev, I.O. Koshevoy, S.P. Tunik, V.P. Ananikov, Design of a Bimetallic Au/Ag System for Dechlorination of Organochlorides: Experimental and Theoretical Evidence for the Role of the Cluster Effect, Organometallics, 2014, Vol. 33, pp. 6003-6012. DOI: 10.1021/om500620u.
44. E.O. Pentsak, E.G. Gordeev, V.P. Ananikov, Noninnocent Nature of Carbon Support in Metal/Carbon Catalysts: Etching/Pitting vs Nanotube Growth under Microwave Irradiation, ACS Catalysis, 2014, Vol. 4, pp. 3806-3814, DOI: 10.1021/cs500934g.
45. O.V. Zatolochnaya, E.G. Gordeev, C. Jahier, V.P. Ananikov, V. Gevorgyan, Carboxylate Switch between Hydro- and Carbopalladation Pathways in Regiodivergent Dimerization of Alkynes, Chemistry – A European Journal, 2014 , Vol. 20, Issue 31, pp. 9578-9588, DOI: 10.1002/chem.201402809.
46. E.G. Gordeev, M.V. Polynski, V.P. Ananikov, «Fast and accurate computational modeling of adsorption on graphene: a dispersion interaction challenge», Phys. Chem. Chem. Phys., 2013, 15, 18815-18821, DOI: 10.1039/c3cp53189a.
47. V.P. Ananikov, E.G. Gordeev, «Novel [4 + 2] cycloaddition reactions of alkyne and enyne key-units: Direct access to bicyclic aromatic and heteroaromatic products. A theoretical mechanistic study», Chemical Science, 2011, 2, 2332-2341, DOI: 10.1039/C1SC00380A.
Hobby:
Computer graphics in the visual arts
