Кашин Алексей

Образование:

2006 - 2011 гг. специалист, Российский химико-технологический университет им. Д.И. Менделеева, Высший химический колледж РАН (ВХК РАН), г. Москва

Аспирантура:

2011 - 2014 гг., Институт органической химии им. Н.Д. Зелинского (ИОХ РАН).

2014 г. - защита кандидатской диссертации.

Область научных интересов:

Металлокомплексный катализ, взаимосвязь между гомогенным и гетерогенным катализом, физические методы исследования каталитических систем, электронная микроскопия.


Публикации:

1. Kashin A. S., Degtyareva E. S., Eremin D. B., Ananikov V. P., "Exploring the performance of nanostructured reagents with organic-group-defined morphology in cross-coupling reaction", Nat. Commun., 2018, 9, 2936. DOI

2. Chernyshev V. M., Khazipov O. V., Shevchenko M. A., Chernenko A. Yu., Astakhov A. V., Eremin D. B., Pasyukov D. V., Kashin A. S., Ananikov V. P., "Revealing the Unusual Role of Bases in Activation/Deactivation of Catalytic Systems: O–NHC Coupling in M/NHC Catalysis", Chem. Sci., 2018, 9, 5564-5577. DOI

3. Azov V. A., Egorova K. S., Seitkalieva M. M., Kashin A. S., Ananikov V. P., ""Solvent-in-Salt" Systems for Design of New Materials in Chemistry, Biology and Energy Research", Chem. Soc. Rev., 2018, 47, 1250-1284. DOI

4. Seitkalieva M. M., Kashin A. S., Egorova K. S., Ananikov V. P., "Ionic Liquids As Tunable Toxicity Storage Media for Sustainable Chemical Waste Management", ACS Sustainable Chem. Eng., 2018, 6, 719–726. DOI

5. Seitkalieva M. M., Kashin A. S., Egorova K. S., Ananikov V. P., "Micro-Scale Processes Occurring in Ionic Liquid–Water Phases During Extraction", Sep. Purif. Technol., 2018, 196, 318-326. DOI

6. Kucherov F.A., Gordeev E.G., Kashin A.S., Ananikov V. P., "3D Printing with Biobased PEF for Carbon Neutral Manufacturing", Angew. Chem. Int. Ed., 2017, 56, 15931 –15935. DOI

7. Werner G., Rodygin K.S., Kostin A.A., Gordeev E.G., Kashin A.S., Ananikov V.P., "A Solid Acetylene Reagent with Enhanced Reactivity: Fluoride-Mediated Functionalization of Alcohols and Phenols", Green Chem., 2017, 19, 3032-3041. DOI

8. Astakhov A.V., Khazipov O.V., Chernenko A.Yu., Pasyukov D.V., Kashin A.S., Gordeev E.G., Khrustalev V.N., Chernyshev V.M., Ananikov V.P., "A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction", Organometallics, 2017, 36, 1981–1992. DOI

9. Kashin A.S., Galkin K.I., Khokhlova E.A., Ananikov V. P., "Direct Observation of Self-Organized Water-Containing Structures in the Liquid Phase and Their Influence on 5-(Hydroxymethyl)furfural Formation in Ionic Liquids", Angew. Chem. Int. Ed., 2016, 55, 2161 –2166. DOI

10. Panova Yu.S., Kashin A.S., Vorobev M.G., Degtyareva E.S., Ananikov V.P., "Nature of the Copper-Oxide-Mediated C−S Cross-Coupling Reaction: Leaching of Catalytically Active Species from the Metal Oxide Surface", ACS Catal., 2016, 6, 3637 – 3643. DOI

11. Bukhtiyarov V.I., Zaikovskii V.I., Kashin A.S., Ananikov V.P.,"Modern electron microscopy in the study of chemical systems at the intersection of organic synthesis and catalysis", Russ. Chem. Rev., 2016, 85, 1198–1214. DOI

12. Pentsak E. O., Kashin A. S., Polynski M. V., Kvashnina K. O., Glatzel P., Ananikov V. P., "Spatial Imaging of Carbon Reactivity Centers in Pd/C Catalytic Systems", Chem. Sci., 2015, 6, 3302-3313. DOI

13. Kashin A.S., Ananikov V. P., "Catalytic C-C and C-Heteroatom Bond Formation Reactions: In Situ Generated or Preformed Catalysts? Complicated Mechanistic Picture Behind Well-Known Experimental Procedures", J. Org. Chem., 2013, 78, 11117-11125. DOI

14. Kashin A. S., Ananikov V. P., "Nano-Structured Metal Chalcogenides as Reagents for the Catalytic Carbon-Sulfur Bond Formation in Cross-Coupling Reaction", Top. Catal., 2013, 56, 1246 - 1252. DOI

15. Zalesskiy S. S., Sedykh A. E., Kashin A. S., Ananikov V. P., "Efficient General Procedure To Access a Diversity of Gold(0) Particles and Gold(I) Phosphine Complexes from a Simple HAuCl4 Source. Localization of Homogeneous/Heterogeneous System's Interface and Field-Emission Scanning Electron Microscopy Study", J. Am. Chem. Soc., 2013, 135, 3550 - 3559. DOI

16. Kachala V. V., Khemchyan L. L., Kashin A. S., Orlov N. V., Grachev A. A., Zalesskiy S. S., Ananikov V. P., "Target-Oriented Analysis of Gaseous, Liquid and Solid Chemical Systems by Mass Spectrometry, Nuclear Magnetic Resonance Spectroscopy and Electron Microscopy", Russ. Chem. Rev., 2013, 82, 648 - 685. DOI

17. Ananikov V.P., Kashin A. S., Hazipov O. V., Beletskaya I. P., Starikova Z. A., "Highly Selective Catalytic Synthesis of E,E-1,4-Diiodobuta-1,3-diene via Atom-Efficient Addition of Acetylene and Iodine. A Versatile E,E-1,3-Diene Building Block in Cross-Coupling Reactions", Synlett, 2011, 2021 - 2024. DOI

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