Alexey Kashin


2006 - 2011 M. Sc., D. Mendeleyev University of Chemical Technology of Russia, Higher Chemical College RAS

2011 - 2014 Ph.D., Zelinsky Institute of Organic Chemistry (ZIOC RAS)

Research interests:

Catalysis, the relationship between homogeneous and heterogeneous catalysis, physical methods for studying catalytic systems, electron microscopy.


1. Kostyukovich A. Yu., Tsedilin A. M., Sushchenko E. D., Eremin D. B., Kashin A. S., Topchiy M. A., Asachenko A. F., Nechaev M. S., Ananikov V. P., "In situ transformations of Pd/NHC complexes to colloidal Pd nanoparticles studied for N-heterocyclic carbene ligands of different nature", Inorg. Chem. Front., 2018, ASAP. DOI

2. Kashin A. S., Degtyareva E. S., Eremin D. B., Ananikov V. P., "Exploring the performance of nanostructured reagents with organic-group-defined morphology in cross-coupling reaction", Nat. Commun., 2018, 9, 2936. DOI

3. Chernyshev V. M., Khazipov O. V., Shevchenko M. A., Chernenko A. Yu., Astakhov A. V., Eremin D. B., Pasyukov D. V., Kashin A. S., Ananikov V. P., "Revealing the Unusual Role of Bases in Activation/Deactivation of Catalytic Systems: O–NHC Coupling in M/NHC Catalysis", Chem. Sci., 2018, 9, 5564-5577. DOI

4. Azov V. A., Egorova K. S., Seitkalieva M. M., Kashin A. S., Ananikov V. P., ""Solvent-in-Salt" Systems for Design of New Materials in Chemistry, Biology and Energy Research", Chem. Soc. Rev., 2018, 47, 1250-1284. DOI

5. Seitkalieva M. M., Kashin A. S., Egorova K. S., Ananikov V. P., "Ionic Liquids As Tunable Toxicity Storage Media for Sustainable Chemical Waste Management", ACS Sustainable Chem. Eng., 2018, 6, 719–726. DOI

6. Seitkalieva M. M., Kashin A. S., Egorova K. S., Ananikov V. P., "Micro-Scale Processes Occurring in Ionic Liquid–Water Phases During Extraction", Sep. Purif. Technol., 2018, 196, 318-326. DOI

7. Kucherov F.A., Gordeev E.G., Kashin A.S., Ananikov V. P., "3D Printing with Biobased PEF for Carbon Neutral Manufacturing", Angew. Chem. Int. Ed., 2017, 56, 15931 –15935. DOI

8. Werner G., Rodygin K.S., Kostin A.A., Gordeev E.G., Kashin A.S., Ananikov V.P., "A Solid Acetylene Reagent with Enhanced Reactivity: Fluoride-Mediated Functionalization of Alcohols and Phenols", Green Chem., 2017, 19, 3032-3041. DOI

9. Astakhov A.V., Khazipov O.V., Chernenko A.Yu., Pasyukov D.V., Kashin A.S., Gordeev E.G., Khrustalev V.N., Chernyshev V.M., Ananikov V.P., "A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction", Organometallics, 2017, 36, 1981–1992. DOI

10. Kashin A.S., Galkin K.I., Khokhlova E.A., Ananikov V. P., "Direct Observation of Self-Organized Water-Containing Structures in the Liquid Phase and Their Influence on 5-(Hydroxymethyl)furfural Formation in Ionic Liquids", Angew. Chem. Int. Ed., 2016, 55, 2161 –2166. DOI

11. Panova Yu.S., Kashin A.S., Vorobev M.G., Degtyareva E.S., Ananikov V.P., "Nature of the Copper-Oxide-Mediated C?S Cross-Coupling Reaction: Leaching of Catalytically Active Species from the Metal Oxide Surface", ACS Catal., 2016, 6, 3637 – 3643. DOI

12. Bukhtiyarov V.I., Zaikovskii V.I., Kashin A.S., Ananikov V.P.,"Modern electron microscopy in the study of chemical systems at the intersection of organic synthesis and catalysis", Russ. Chem. Rev., 2016, 85, 1198–1214. DOI

13. Pentsak E. O., Kashin A. S., Polynski M. V., Kvashnina K. O., Glatzel P., Ananikov V. P., "Spatial Imaging of Carbon Reactivity Centers in Pd/C Catalytic Systems", Chem. Sci., 2015, 6, 3302-3313. DOI

14. Kashin A.S., Ananikov V. P., "Catalytic C-C and C-Heteroatom Bond Formation Reactions: In Situ Generated or Preformed Catalysts? Complicated Mechanistic Picture Behind Well-Known Experimental Procedures", J. Org. Chem., 2013, 78, 11117-11125. DOI

15. Kashin A. S., Ananikov V. P., "Nano-Structured Metal Chalcogenides as Reagents for the Catalytic Carbon-Sulfur Bond Formation in Cross-Coupling Reaction", Top. Catal., 2013, 56, 1246 - 1252. DOI

16. Zalesskiy S. S., Sedykh A. E., Kashin A. S., Ananikov V. P., "Efficient General Procedure To Access a Diversity of Gold(0) Particles and Gold(I) Phosphine Complexes from a Simple HAuCl4 Source. Localization of Homogeneous/Heterogeneous System's Interface and Field-Emission Scanning Electron Microscopy Study", J. Am. Chem. Soc., 2013, 135, 3550 - 3559. DOI

17. Kachala V. V., Khemchyan L. L., Kashin A. S., Orlov N. V., Grachev A. A., Zalesskiy S. S., Ananikov V. P., "Target-Oriented Analysis of Gaseous, Liquid and Solid Chemical Systems by Mass Spectrometry, Nuclear Magnetic Resonance Spectroscopy and Electron Microscopy", Russ. Chem. Rev., 2013, 82, 648 - 685. DOI

18. Ananikov V.P., Kashin A. S., Hazipov O. V., Beletskaya I. P., Starikova Z. A., "Highly Selective Catalytic Synthesis of E,E-1,4-Diiodobuta-1,3-diene via Atom-Efficient Addition of Acetylene and Iodine. A Versatile E,E-1,3-Diene Building Block in Cross-Coupling Reactions", Synlett, 2011, 2021 - 2024. DOI