Alexey Kashin

Education and research experience:

2006 – 2011: M.Sc. student, D. Mendeleyev University of Chemical Technology of Russia, Higher Chemical College RAS, Moscow;

2011: M.Sc. in Chemistry;

2011 – 2014: Ph.D. student, Zelinsky Institute of Organic Chemistry RAS;

2014: Ph.D. in Organic Chemistry;

2015 – 2017: Researcher, Zelinsky Institute of Organic Chemistry RAS;

2017 – present: Senior researcher, Zelinsky Institute of Organic Chemistry RAS.

Research interests:

Transition?metal catalysis, chemistry of disperse systems, electron microscopy, X-ray spectroscopy.


1. Boiko D.A., Kashin A.S., Sorokin V.R., Agaev Yu.V., Zaitsev R.G., Ananikov V.P., "Analyzing ionic liquid systems using real-time electron microscopy and a computational framework combining deep learning and classic computer vision techniques", J. Mol. Liq., 2023, 376, 121407. [DOI]

2. Egorova K.S., Seitkalieva M.M., Kashin A.S., Gordeev E.G., Vavina A.V., Posvyatenko A.V., Ananikov V.P., "Biological activity, solvation properties and microstructuring of protic imidazolium ionic liquids", J. Mol. Liq., 2022, 367, Part A, 120450. [DOI]

3. Kashin A.S., Boiko D.A., Ananikov V.P., "Neural network analysis of electron microscopy video data reveals the temperature?driven microphase dynamics in the ions/water system", Small, 2021, 2007726. [DOI]

4. Kashin A.S., Ananikov V.P., "Nanoscale advancement continues – from catalysts and reagents to restructuring of reaction media", Angew. Chem. Int. Ed., 2021, 60, 35, 18926-18928. [DOI]

5. Kashin A.S., Degtyareva E.S., Ananikov V.P., "Visualization of the mechanical wave effect on liquid microphases and its application for the tuning of dissipative soft microreactors", JACS Au, 2021, 1, 1, 87-97. [DOI]

6. Seitkalieva M.M., Vavina A.V., Posvyatenko A.V., Egorova K.S., Kashin A.S., Gordeev E.G., Strukova E.N., Romashov L.V., Ananikov V.P., "Biomass-derived ionic liquids based on a 5HMF platform chemical: Synthesis, characterization, biological activity, and tunable interactions at the molecular level", ACS Sustainable Chem. Eng., 2021, 9, 9, 3552-3570. [DOI]

7. Galushko A.S., Gordeev E.G., Kashin A.S., Zubavichus Ya.V. and Ananikov V.P., "Visualization of catalyst dynamics and development of a practical procedure to study complex "cocktail"-type catalytic systems ", Faraday Discuss., 2021, 229, 458-474. [DOI]

8. Kucherov F.A., Gordeev E.G., Kashin A.S., Ananikov V.P., "Controlled natural biomass deoxygenation allows the design of reusable hot-melt adhesives acting in a multiple oxygen binding mode", ACS Appl. Mater. Interfaces, 2020, 12, 40, 45394-45403. [DOI]

9. Kashin A.S., Galushko A.S., Degtyareva E.S., Ananikov V.P., "Solid-state C-S coupling in nickel organochalcogenide frameworks as a route to hierarchical structure transfer to binary nanomaterials", Inorg. Chem., 2020, 59, 15, 10835-10844. [DOI]

10. Egorova K.S., Posvyatenko A.V., Fakhrutdinov A.N., Kashin A.S., Ananikov V.P., "Assessing possible influence of structuring effects in solution on cytotoxicity of ionic liquid systems", J. Mol. Liq., 2020, 111751. [DOI]

11. Kashin A.S., Ananikov V.P., "Monitoring chemical reactions in liquid media using electron microscopy", Nat. Rev. Chem., 2019, 3, 624-637 [DOI]

12. Titov K., Eremin D.B., Kashin A.S., Boada R., Souza B.E., Kelley C.S., Frogley M.D., Cinque G., Gianolio D., Cibin G., Rudi? S., Ananikov V.P., Tan J.C., "OX-1 metal-organic framework nanosheets as robust hosts for highly active catalytic palladium species", ACS Sustainable Chem. Eng., 2019, 7, 5875-5885. [DOI]

13. Egorova K.S., Sinjushin A.A., Posvyatenko A.V., Eremin D.B., Kashin A.S., Galushko A.S., Ananikov V.P., "Evaluation of phytotoxicity and cytotoxicity of industrial catalyst components (Fe, Cu, Ni, Rh and Pd): A case of lethal toxicity of a rhodium salt in terrestrial plants", Chemosphere, 2019, 223, 738-747. [DOI]

14. Degtyareva E.S., Erokhin K.S., Kashin A.S., Ananikov V.P., "Switchable Ni-catalyzed bis-thiolation of acetylene with aryl disulfides as an access to functionalized alkenes and 1,3-dienes", Appl. Catal. A Gen., 2019, 571, 170-179. [DOI]

15. Kostyukovich A.Yu., Tsedilin A.M., Sushchenko E.D., Eremin D.B., Kashin A.S., Topchiy M.A., Asachenko A.F., Nechaev M.S., Ananikov V.P., "In situ transformations of Pd/NHC complexes to colloidal Pd nanoparticles studied for N-heterocyclic carbene ligands of different nature", Inorg. Chem. Front., 2019, 6, 482-492. [DOI]

16. Kashin A.S., Degtyareva E.S., Eremin D.B., Ananikov V.P., "Exploring the performance of nanostructured reagents with organic-group-defined morphology in cross-coupling reaction", Nat. Commun., 2018, 9, 2936. [DOI]

17. Chernyshev V.M., Khazipov O.V., Shevchenko M.A., Chernenko A.Yu., Astakhov A.V., Eremin D.B., Pasyukov D.V., Kashin A.S., Ananikov V.P., "Revealing the unusual role of bases in activation/deactivation of catalytic systems: O-NHC coupling in M/NHC catalysis", Chem. Sci., 2018, 9, 5564-5577. [DOI]

18. Azov V.A., Egorova K.S., Seitkalieva M.M., Kashin A.S., Ananikov V.P., ""Solvent-in-salt" systems for design of new materials in chemistry, biology and energy research", Chem. Soc. Rev., 2018, 47, 1250-1284. [DOI]

19. Seitkalieva M.M., Kashin A.S., Egorova K.S., Ananikov V.P., "Ionic liquids as tunable toxicity storage media for sustainable chemical waste management", ACS Sustainable Chem. Eng., 2018, 6, 719-726. [DOI]

20. Seitkalieva M.M., Kashin A.S., Egorova K.S., Ananikov V.P., "Micro-scale processes occurring in ionic liquid-water phases during extraction", Sep. Purif. Technol., 2018, 196, 318-326. [DOI]

21. Kucherov F.A., Gordeev E.G., Kashin A.S., Ananikov V.P., "3D printing with biobased PEF for carbon neutral manufacturing", Angew. Chem. Int. Ed., 2017, 56, 15931-15935. [DOI]

22. Werner G., Rodygin K.S., Kostin A.A., Gordeev E.G., Kashin A.S., Ananikov V.P., "A solid acetylene reagent with enhanced reactivity: Fluoride-mediated functionalization of alcohols and phenols", Green Chem., 2017, 19, 3032-3041. [DOI]

23. Astakhov A.V., Khazipov O.V., Chernenko A.Yu., Pasyukov D.V., Kashin A.S., Gordeev E.G., Khrustalev V.N., Chernyshev V.M., Ananikov V.P., "A new mode of operation of Pd-NHC systems studied in a catalytic Mizoroki–Heck reaction", Organometallics, 2017, 36, 1981-1992. [DOI]

24. Bukhtiyarov V.I., Zaikovskii V.I., Kashin A.S., Ananikov V.P., "Modern electron microscopy in the study of chemical systems at the intersection of organic synthesis and catalysis", Russ. Chem. Rev., 2016, 85, 1198-1214. [DOI]

25. Panova Yu.S., Kashin A.S., Vorobev M.G., Degtyareva E.S., Ananikov V.P., "Nature of the copper-oxide-mediated C-S cross-coupling reaction: Leaching of catalytically active species from the metal oxide surface", ACS Catal., 2016, 6, 3637-3643. [DOI]

26. Kashin A.S., Galkin K.I., Khokhlova E.A., Ananikov V.P., "Direct observation of self-organized water-containing structures in the liquid phase and their influence on 5(hydroxymethyl)furfural formation in ionic liquids", Angew. Chem. Int. Ed., 2016, 55, 2161-2166. [DOI]

27. Pentsak E.O., Kashin A.S., Polynski M.V., Kvashnina K.O., Glatzel P., Ananikov V.P., "Spatial imaging of carbon reactivity centers in Pd/C catalytic systems", Chem. Sci., 2015, 6, 3302-3313. [DOI]

28. Kashin A.S., Ananikov V.P., "Catalytic C-C and C-heteroatom bond formation reactions: In situ generated or preformed catalysts? Complicated mechanistic picture behind well-known experimental procedures", J. Org. Chem., 2013, 78, 11117-11125. [DOI]

29. Kashin A.S., Ananikov V.P., "Nano-structured metal chalcogenides as reagents for the catalytic carbon-sulfur bond formation in cross-coupling reaction", Top. Catal., 2013, 56, 1246-1252. [DOI]

30. Zalesskiy S.S., Sedykh A.E., Kashin A.S., Ananikov V.P., "Efficient general procedure to access a diversity of gold(0) particles and gold(I) phosphine complexes from a simple HAuCl4 source. Localization of homogeneous/heterogeneous system's interface and field-emission scanning electron microscopy study", J. Am. Chem. Soc., 2013, 135, 3550-3559. [DOI]

31. Kachala V.V., Khemchyan L.L., Kashin A.S., Orlov N.V., Grachev A.A., Zalesskiy S.S., Ananikov V.P., "Target-oriented analysis of gaseous, liquid and solid chemical systems by mass spectrometry, nuclear magnetic resonance spectroscopy and electron microscopy", Russ. Chem. Rev., 2013, 82, 648 - 685. [DOI]

32. Ananikov V.P., Kashin A.S., Hazipov O.V., Beletskaya I.P., Starikova Z.A., "Highly selective catalytic synthesis of E,E-1,4-diiodobuta-1,3-diene via atom-efficient addition of acetylene and iodine. A versatile E,E-1,3-diene building block in cross-coupling reactions", Synlett, 2011, 2021-2024. [DOI]

33. Kashin A.S., Ananikov V.P., "A SEM study of nanosized metal films and metal nanoparticles obtained by magnetron sputtering", Russ. Chem. Bull. Int. Ed., 2011, 60, 2602-2607. [DOI]