Publications

Selected     Show All     2024     2023     2022     2021     2020     2019     2018     2017     2016     2015     2014     2013     2012     2011     2010     2009     2008     2007     2006     2005     2004     2003     2002     2001     2000     1998     1997     

The Mechanism of C-C Bond Formation on the Pt(IV) Center Involving Chelate Metallocycle Ligands

Ananikov V.P., Mitchenko S.A., Beletskaya I.P., J.Organomet.Chem., 2000, 604, 290-295.
DOI link

An unusual fact of C-C reductive elimination reaction in bis-chelated Pt(IV) complexes under mild conditions was studied. It has been shown that breaking at least one of the chelate rings is required to promote a carbon-carbon bond formation reaction. An intermediate complex, which resulted from a chelate ligand breaking process, was detected directly in the reaction mixture using 2D 1H–195Pt heteronuclear NMR spectroscopy.